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Why isn't cold brew just hot coffee cooled over ice?

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Answer: Different extraction

Different extractionRight. Brewing is a solid-liquid extraction: water pulls different soluble and suspended compounds from roasted grounds. A hot brew has already used high heat to pull a fast, broad chemical mix before you chill it. Cold brew starts with room-temperature or cold water for hours, so its profile can diverge from iced hot coffee.

Ice removes caffeineNot quite. Ice chills and dilutes; it does not selectively remove caffeine from a finished drink. Caffeine extraction depends on recipe, grind, time, temperature, and coffee dose. If a cold coffee feels gentler, the mechanism is more likely the extraction profile and dilution, not ice filtering caffeine out.

Sugar forms overnightNot quite. Cold brew sitting overnight is not fermenting into a sweeter drink under normal brewing practice. The sweet impression is mostly aroma and reduced sour/bitter masking, while longer contact can actually increase dissolved solids and titratable acidity. Overnight time changes extraction, not sugar manufacture.

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