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Why does bread get hard when stale?

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Answer: Starch molecules recrystallize

Starch molecules recrystallizeCorrect! Fresh bread has gelatinized starch (soft, dispersed). Over time, starch molecules rearrange into crystalline structures (retrogradation), making bread firm. This happens even in sealed bags! Toasting or microwaving temporarily disrupts crystals, refreshing bread. Interestingly, refrigeration speeds staleness; freezing prevents it!

Yeast dies and hardensWrong. Yeast is inactive after baking. Staleness is from starch structural changes, not yeast condition.

Gluten proteins tightenWrong. Gluten provides structure but doesn't cause staleness. Starch retrogradation is the culprit—molecules reorganizing after baking.

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